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Ethylene-Methyl Acrylate Copolymer(EMA)

    • Product Name Ethylene-Methyl Acrylate Copolymer(EMA)
    • Chemical Name (IUPAC) Poly(ethene-co-methyl prop-2-enoate)
    • CAS No. 9010-92-8
    • Chemical Formula (C2H4)x·(C5H8O2)y
    • Form/Physical State Solid pellets
    • Factory Site Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry sales3@liwei-chem.com
    • Manufacturer Anhui Liwei Chemical Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    675409

    Chemical Formula [(C2H4)x-(C5H8O2)y]n
    Appearance Translucent to opaque pellets
    Density 0.93–0.96 g/cm³
    Melt Flow Index 0.5–30 g/10 min (varies by grade)
    Shore Hardness 40–95 A
    Glass Transition Temperature -20 to -35°C
    Melting Point 70–95°C
    Tensile Strength 6–24 MPa
    Elongation At Break 400–900%
    Water Absorption <0.1%
    Thermal Conductivity 0.32 W/m·K
    Flammability Combustible, UL94 HB
    Weather Resistance Good
    Dielectric Constant 2.3–2.5 at 1 kHz
    Processing Methods Injection molding, extrusion, blow molding

    As an accredited Ethylene-Methyl Acrylate Copolymer(EMA) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Ethylene-Methyl Acrylate Copolymer (EMA) is packaged in 25 kg multi-layered plastic bags, ensuring moisture resistance and safe transport.
    Container Loading (20′ FCL) Container loading (20′ FCL) for Ethylene-Methyl Acrylate Copolymer (EMA): 16–18 metric tons packed in 25kg bags, palletized or loose.
    Shipping Ethylene-Methyl Acrylate Copolymer (EMA) is shipped in moisture-proof, sealed polyethylene bags or drums, typically ranging from 25 kg to bulk quantities. Store and transport in a cool, dry area, away from direct sunlight and heat sources. Ensure containers are tightly closed to prevent contamination and degradation during transit.
    Storage Ethylene-Methyl Acrylate Copolymer (EMA) should be stored in a cool, dry, and well-ventilated area, away from direct sunlight and sources of heat or ignition. Keep the material in tightly closed original containers to prevent contamination. Avoid exposure to strong oxidizing agents. Proper storage ensures product stability, minimizes degradation, and maintains safe handling conditions.
    Shelf Life Ethylene-Methyl Acrylate Copolymer (EMA) typically has a shelf life of 12-24 months when stored in cool, dry conditions.
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    Certification & Compliance
    More Introduction

    Ethylene-Methyl Acrylate Copolymer (EMA): Reliable Performance, Real-World Advantages

    Introduction to Our EMA Copolymer

    Years of hands-on experience in the field have given our team a deep understanding of the shifting needs across multiple manufacturing sectors. With decades of focused research and continuous feedback from factory lines, we have developed our Ethylene-Methyl Acrylate Copolymer (EMA), built with attention to detail and tested under a range of production environments. Our current model range includes different methyl acrylate (MA) contents, with popular grades spanning typical MA content from 15% up to 28%. This broad range supports production needs in cable insulation, extrusion coatings, blended polymer systems, and adhesive applications.

    Producing EMA in-house allows us to control each stage, from raw material selection through final pellet inspection. Purity isn’t just an abstract metric—we maintain exacting standards for polymerization to ensure that each batch brings the consistency converters and compounders depend on. Niche clients sometimes seek narrower melt-flow rate (MFR) windows, and our technicians know how tight viscosity controls can make or break a run on modern high-speed lines. Our granules flow smoothly and dispense cleanly, reducing dust, clumping, and hang-ups in feeder systems.

    Why EMA Deserves Attention

    EMA offers a straightforward combination of flexibility and toughness that many materials can’t match. We see cable manufacturers, flexible packaging producers, and specialty engineering plastics processors come back to EMA because it stands up to repeated stress, bending, and twisting, all while resisting cracking at low temperatures. EMA forms a middle ground between polyethylenes and more brittle copolymers, sidestepping the stiffness of EVA and the processability hassles of ethylene-acrylic acid blends.

    Choosing the right polymer always comes down to the job at hand. Consider a cable sheath: installers want pliability when routing cables through confined spaces, but also a jacket that shrugs off abrasion, maintains color, and resists environmental stress cracking. Higher-methyl acrylate EMA grades deliver those needs while running cleanly over both older and newer production lines, whether for cable, extrusion lamination, or foam sheeting.

    Adhesive makers often compare EMA to EVA or EAA, looking for something that blends softness, low glass transition temperature, and hot-melt compatibility. EMA’s structure lets adhesive formulations bond well to metal, polar plastics, papers, and even some varnishes. In low-smoke, halogen-free flame retardant cable compounds, EMA offers not just flexibility but also compatibility with traditional ATH and MDH filler systems.

    Key Properties from a Producer's Perspective

    We run our own test extruders, and firsthand evaluation on pilot lines gives us a clear picture of EMA behavior. Such on-site trials show why compounders rate EMA as an excellent impact modifier for polyolefins. Adding EMA to high-density polyethylene or polypropylene raises impact resistance without pushing costs sky-high or rendering the finished part sticky or soft.

    At lower methyl acrylate contents—15% to 20%—EMA copolymers maintain good tensile strength and surface hardness, yet still allow for some softness not found in straight polyethylenes. As methyl acrylate increases, flexibility grows and processing temperatures drop, which aids in extrusion coating of delicate films and foils. Powder coatings manufacturers appreciate the melt flow characteristics of middle-range grades, as they are workable using both conventional hot-melt applicators and more specialized equipment.

    On the electrical side, EMA’s dielectric strength fits well in insulation and jacketing where both flexibility and electrical properties matter. Our experience shows that wire extruders moving to EMA often report reduced scrap rates and easier color masterbatch dispersion, especially at higher throughputs.

    EMA Versus Other Polymers

    Much gets said in the industry about swapping similar acrylate copolymers, but practice on the production floor reveals notable differences. EVA (Ethylene-Vinyl Acetate) remains popular for certain cable and footwear compounds. Yet EVA, with its crystalline tendency and higher glass transition temperature, runs stiffer than most EMA grades at low temperatures. EMA compounds flex better in cold climates, and we routinely see fewer stress cracks and embrittlement when sub-zero testing is done.

    Ethylene-Acrylic Acid (EAA) can excel in certain coatings and adhesives thanks to superior polarity and adhesion, yet EAA’s ionic character can bring unwanted moisture uptake and processing corrosion. EMA sidesteps these problems, delivering the right mix of toughness, clarity, and moisture resistance without the drawbacks of acid copolymer corrosion or shorter shelf life.

    Common packaging grades of linear low-density polyethylene blend easily with EMA to improve softness in stretch and shrink films, but customers mention that pure LLDPE films lack the elasticity and recovery seen when EMA comes into play. Blends of EMA with polypropylene bolster hinges in living components and add softness to otherwise rigid parts. Our technical service team has worked with clients to tune these alloys for both injection and extrusion molding, balancing processability and final properties based on real product samples, not just datasheet numbers.

    Specifications—What Matters for Daily Production

    Producers and processors regularly ask about melt index, density, and MA content, since these factors govern how a batch will behave under practical conditions. For extrusion, the melt flow rate window usually falls between 2 and 15 g/10 min (190°C, 2.16 kg), with a density range of 0.930 to 0.950 g/cm³. This gives processors a flexible starting point for calendaring, blow-molding, sheet extrusion, and compounding.

    We have invested in on-line monitoring and lab-scale QC tools to ensure every pallet of EMA achieves target density and MFR. Each model of EMA runs true to its intended purpose—higher melt indexes for hot melt adhesives, medium for cable and coating, and lower grades for injection molding or blending. Years of troubleshooting for customers in extrusion and cable production have taught us that minor variations in MFR can play havoc with processing windows, so we control batch consistency to tight limits.

    Acrylate content greatly influences both softness and polarity. Lower MA grades work well where high clarity and a stiffer touch are required, while grades with higher methyl acrylate content lend extra flexibility and heat sealing performance. We observed that clients in the medical packaging industry will almost always favor higher-MA EMA for its improved hermetic seal quality and low odor.

    Industry Applications: Successes and Common Questions

    Our senior plant operators have built up thousands of hours working with EMA over the years, rolling out tons of the material for both home and export markets. Over time, a few questions keep coming back: Will EMA run cleanly on existing extrusion or molding tools? Are there known issues when switching from EVA or PE to EMA? How can unwanted gel formation be avoided?

    EMA granules require no dramatic equipment changes for most extrusion, injection, or compounding lines that already process similar materials. Still, tuning screw design or adjusting temperature profiles unlocks optimal output. For many film and cable plants, we collaborate on trials to recommend barrel temperatures—starting around 130°C and raising up to 220°C depending on the batch and application. Our application team has seen that extended residence times above 250°C can cause slight yellowing and increased gels, so we guide our customers to manage throughput speeds and minimize dead spots.

    Blending EMA into recycled-polyethylene and post-consumer resin offers a performance upgrade without forsaking sustainability. EMA improves impact and elongation, helping converters bring otherwise downgraded recyclate back into the loop for higher-value parts. As government and consumer interest increases in recyclable, long-lasting materials, EMA stands out as a practical upgrade for processors looking to strengthen circular economy credentials.

    Compounding Insights: What Works

    Chemical compatibility always matters. Throughout years of collaborative trials with wire, cable, and hose producers, our specialists fine-tuned masterbatch addition—EMA disperses colorants and stabilizers easily, avoiding streaks or agglomerates. This advantage shows up clearest in HALS (hindered amine light stabilizer) and UV additive systems, as EMA’s structure allows robust mixing. In flame retardant systems, EMA blends seamlessly with ATH or other non-halogenated FR additives, boosting flexibility and helping formulas meet severe cable test standards like UL 1581 or IEC 60332.

    Hot melt adhesives based on EMA run at lower temperatures than pure PE or PP, offering clean melting and fast set times. Our clients in packaging and bookbinding often report faster cycle times, less char formation, and better bonding over a range of surfaces. Wood effect foils, laminates, and even hard-to-bond metals stick well with EMA-based adhesives, letting converters handle more product types with minimal equipment changes.

    Over repeated runs, the softer grades of EMA demonstrate resilience against flexural fatigue. One customer in the automotive grommet sector reported drop-in implementation of EMA to upgrade flexibility and aging performance without a hike in cycle times. The shift not only trimmed scrap but also yielded better finished part feel—softer touch, less white stress marking, better fit.

    Processing Experience and Practical Wisdom

    Decades on the factory floor teach lessons that no manual ever covers. We’ve learned to scrutinize pellet size and surface gloss; tacky, uneven granules don’t feed right, leading to blockages, wasted time, and unnecessary cleaning. Our plant maintains strict screening against oversized or fused pieces. Bulk silos and automatic feeders get more predictable behavior from our EMA, with accurate dosing and balanced plasticizer absorption in pre-blends.

    For wire and cable, clients need not only cable elongation but also color retention, flexibility, and stress crack resistance. It’s this blend of mechanical integrity and process flexibility that EMA delivers. Compared to EVA, which sometimes embrittles on repeated field bending, or EAA with its moisture sensitivity, EMA ages with greater resilience under UV and ozone conditions. This fact keeps OEMs confident in field performance years down the line.

    Processors working with metallocene PE and other high-performance resins have found that small amounts of EMA improve seal strength and puncture resistance in multilayer films. Our production batches show that, in co-extrusion, EMA interfaces cleanly with other polyolefins and polar polymers, boosting sealing and delamination resistance without major modifications to the extrusion set-up or layer sequencing.

    The packaging sector sees clear value in EMA’s improved heat seal properties. EMA’s flexible structure drops the seal initiation temperature, reducing energy consumption and material shrinkage. Specialty bag producers and medical packagers mention fewer seal failures, stronger peelable seals, and more reliable pouch closure.

    Environmental Challenges and Solutions

    The push for more sustainable, recyclable plastics continues to redefine business decisions. As plastics producers, we feel a responsibility to help shape this trend. EMA does not contain halogens or heavy metals and can be safely blended with polyolefin-based recyclate streams without causing phase separation or excessive melt viscosity. We share detailed compatibility and recycling guidance, based on our own pellet refeed studies, to boost recycled content while maintaining physical properties.

    Interest in bio-based and “green” acrylates rises every year. Our R&D team has started trials with certified bio-ethylene for pilot batches, bringing more sustainable feedstocks into large-volume EMA production. While technical limits still exist for broad adoption, early results suggest it’s possible to create EMA copolymers with partial biological origin without losing touch, performance, or process efficiency.

    Issues and Solutions from an Insider’s View

    Gel formation, color drift, blocked die heads—these are real headaches for processor and manufacturer alike. Consistency in copolymerization, as well as raw material purity, cut down on the most common process snags. Our plant’s filtration and devolatilization systems ensure minimal gel speck contamination, while automated peroxide or initiator addition ensures every lot gets identical conversion control. By keeping a short feedback loop between production and QC, out-of-spec material never reaches the warehouse.

    Static buildup in dry air handling systems happens more frequently with heat-softened copolymers like EMA. We advise inline ionizing bars and careful grounding of handling systems to prevent fines buildup or unexpected flow stoppages. Many customers using pneumatic conveying have reduced lost time and maintenance costs using our bulk handling guidelines, drawn directly from daily heavy-duty silo shifts and thousands of tonnes processed each year.

    Odor, particularly in high-acrylate grades, matters for packaging and medical markets. Our team maintains tight controls on residual monomer and impurity content, leading to films and coatings with low off-odor and no residual “acrylate” smell. In controlled shelf-life studies, EMA-blended parts maintain odor acceptability better than comparable adhesives and coatings based on EVA or EAA.

    Continuing Development and Customer Support

    Standing behind our material means more than just selling pellets. Frequent field visits and technical troubleshooting help address ongoing challenges. Our approach centers on solving real-world usage problems by rapid analysis, whether it’s unexpected melt fracture on a new die, surface finish issues in foamed EVA blends, or interlayer adhesion problems in multilayer film. End customers benefit from lower defect rates, longer production runs between cleaning cycles, and less waste—outcomes that come only through experience, not from simply copying data sheets.

    The Road Ahead—Bridging Performance Needs with EMA

    Every innovation in polymer science pushes manufacturers to rethink old habits and tune their formulations for new needs. We continue to work closely with partners in automotive, wire and cable, flexible packaging, footwear, and adhesives, building not just robust supply chains but robust technical collaborations. EMA copolymers—once considered niche—practically prove their worth every day in millions of durable, reliable, and flexible products worldwide.

    By investing in thoughtful design, careful polymerization control, and deep practical experience, we meet today’s market expectations for performance, reliability, and process smoothness. As trends in product miniaturization, improved cable flexibility, and environmental safety grow stronger, EMA stands ready to handle the job, mile after mile, run after run, package after package.