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Tetrabromophthalic Anhydride(TBPA)

    • Product Name Tetrabromophthalic Anhydride(TBPA)
    • Chemical Name (IUPAC) 4,5,6,7-tetrabromo-2-benzofuran-1,3-dione
    • CAS No. 632-79-1
    • Chemical Formula C8Br4O3
    • Form/Physical State Powder/Solid
    • Factory Site Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry sales3@liwei-chem.com
    • Manufacturer Anhui Liwei Chemical Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    489173

    Chemicalname Tetrabromophthalic Anhydride
    Abbreviation TBPA
    Casnumber 632-79-1
    Molecularformula C8Br4O3
    Molecularweight 485.61 g/mol
    Appearance White to off-white crystalline powder
    Meltingpoint 272-275°C
    Boilingpoint Decomposes before boiling
    Solubilityinwater Insoluble
    Density 2.8 g/cm³
    Flashpoint Non-flammable
    Purity Typically >98%
    Odor Odorless
    Stability Stable under recommended storage conditions
    Mainuse Flame retardant in plastics and resins

    As an accredited Tetrabromophthalic Anhydride(TBPA) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Tetrabromophthalic Anhydride (TBPA) is packaged in a 25 kg fiber drum with inner polyethylene lining for moisture protection.
    Container Loading (20′ FCL) 20′ FCL loading of Tetrabromophthalic Anhydride (TBPA): packed in sealed fiber drums, 10-12 MT per container, moisture-proof, tightly secured.
    Shipping **Tetrabromophthalic Anhydride (TBPA)** is shipped in tightly sealed, chemical-resistant containers, typically drums or fiberboard boxes with inner liners, to prevent moisture absorption. It should be labeled according to hazardous materials regulations, protected from heat and humidity, and transported by authorized carriers compliant with environmental and safety guidelines.
    Storage Tetrabromophthalic Anhydride (TBPA) should be stored in a tightly sealed container, in a cool, dry, and well-ventilated area away from heat and direct sunlight. Keep it isolated from incompatible substances such as strong bases and oxidizing agents. Ensure the storage area is clearly labeled, equipped for chemical containment, and access is limited to authorized personnel. Avoid moisture exposure.
    Shelf Life Tetrabromophthalic Anhydride (TBPA) typically has a shelf life of 2–3 years if stored cool, dry, and tightly sealed.
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    Certification & Compliance
    More Introduction

    Tetrabromophthalic Anhydride (TBPA): Direct From The Manufacturer’s Perspective

    Our Experience With TBPA Production

    Years of making brominated flame retardants have taught us a lot about what works in demanding material applications. Tetrabromophthalic anhydride, or TBPA, has built a reputation for tough, reliable performance where flame resistance counts. Our team handles every stage of its production, from bromination to purification, with a steady focus on purity and consistency you can trust. Over time, we’ve refined methods for controlling reaction temperature, handling byproducts, and waste minimization, which not only ensures consistent purity but addresses safety and compliance before the product leaves our site. Direct access to the entire process gives us the kind of control downstream users rarely see, and we stand behind the TBPA that comes from our facilities.

    The Properties That Matter

    TBPA carries a bromine content that plays a central role in its fire retardant capability, particularly in engineered plastics and polyester resins. The molecular structure—with four tightly bound bromine atoms—interrupts the combustion process, releasing brominated radicals that absorb energy and starve the flame of free radicals. In practice, the white to off-white crystalline powder blends smoothly with most polyesters, epoxy resins, and unsaturated polyester molding compounds, offering high thermal stability without breaking down at typical processing temperatures. We monitor moisture content and acidity closely, as both can affect resin compatibility and long-term material behavior.

    How TBPA Fits Today’s Safety And Environmental Landscape

    There’s always a push and pull between safety standards and environmental responsibility in the flame retardant sector. Our TBPA stands out because it provides flame retardance at relatively low loading levels, so end-users maintain the mechanical and aesthetic qualities of their base polymers. Compared to many legacy halogenated products, TBPA releases fewer volatile organic compounds during processing and in fire scenarios, addressing community concerns over toxic byproducts. With growing regulatory focus on end-of-life polymer waste and hazardous substances, TBPA offers a balance: it meets high fire resistance requirements while reducing the volume of additive needed. We keep a sharp eye on international regulations, especially for electronics and automotive materials, to ensure our TBPA supports compliance as standards continue to evolve.

    Where TBPA Excels

    Some flame retardants leave users chasing a compromise between fire resistance and mechanical performance. Our clients in the thermoset and thermoplastic resin industries come to TBPA for exactly this reason. The product disperses evenly in polyester granules and melts, either via direct compounding or in powder mixing operations. TBPA works especially well in glass fiber-reinforced polyester, where it doesn’t weaken finished parts or cause surface defects. For electrical insulators, circuit boards, switch housings, and automobile fabrics, the combination of high bromine content and low impurity levels allows reliable downstream molding or extrusion, limiting batch-to-batch variability.

    We also see rapid uptake in epoxy resin-based systems—particularly for laminates in printed circuit boards. In these applications, the performance metrics are clear: TBPA-enriched resins reach higher Limiting Oxygen Index (LOI) values, meeting industry thresholds for delayed ignition and reduced smoke density. A big point for many of our partners lies in TBPA’s low contribution to corrosion during lamination or reflow soldering, especially when compared with some alternative flame retardants that carry higher halogen or acidity contaminants.

    Specification—What Our Customers See

    Our TBPA is most often supplied as a powder, with granule particle sizes tailored for resin compounding. Near-complete bromination and carefully managed anhydride content set the product apart from those offered by resellers. We pay particular attention to bulk density, which can impact feeding rates in automated systems. Each batch undergoes full titration and gas chromatography analysis to verify assay percentages of bromine and anhydride—two indicators that track directly with real-world fire retardant performance. High-purity output remains the benchmark, so you won’t find byproduct phthalates or excess acid left lurking in the finished material. We routinely measure water content and residual color, since off-standard values could show up as process fouling or product darkening downstream.

    How TBPA Compares to Other Flame Retardants

    Working directly with end-users, we see how choices among flame retardants affect not just product safety but every step from compounding to recycling. Antimony trioxide, for example, costs less per kilo, but requires much higher loadings to deliver the same flame resistance. This means heavier finished goods, more handling, and often a hit to transparency or color in molded parts.

    Decabromodiphenyl ether (DecaBDE) played a significant role in legacy fire retardant systems, but worldwide restrictions and phase-outs have left many looking for safer candidates. TBPA doesn’t persist in the environment the way DecaBDE has been shown to, and the migration risk into waterways or the workplace is far lower. Compared to hexabromocyclododecane (HBCD)—once popular in expanded and extruded polystyrene insulation—TBPA provides similar flame retardant effects, but with greater compatibility in polyesters and epoxies, and without raising the red flags for bioaccumulation and toxicity.

    For resins that can’t tolerate phosphate esters, or where phosphates can catalyze aging or yellowing, TBPA serves as an essential option that's free from phosphorus or nitrogen. Its thermal and chemical stability during molding and extended life under field conditions have been proven through our customers’ demanding test suites. Even after repeated cycles under load, TBPA-containing composites display stable flame resistance, mechanical strength, and limited discoloration—something we track with every major support client in construction panels or mass transit systems.

    Troubleshooting and Process Experience

    Those who compound at scale know about the headaches that come from dusting, bridging, or moisture pick-up. Our process leaves TBPA with optimized particle distribution. This reduces caking and keeps dust at bay during pneumatic conveying. On production floors, excessive fines can affect weighing and cause airborne concentration issues, so we calibrate milling and drying equipment to limit these risks.

    Thermal stability means less gassing or corrosion during resin melt cycles, which helps safeguard both extruder hardware and molds from premature wear. We speak frequently with clients scaling up to multi-ton lots about this advantage, because equipment downtime is money lost. Our technical contacts have seen that by controlling incoming moisture and acidity specifications, TBPA-based compounds retain their flow properties without needing additional antacids or pH adjusters that would otherwise slow the process or complicate compliance documentation.

    The Manufacturing Difference

    Responsibility for quality and consistency lands squarely with us. Unlike dealers or regional packagers, the direct manufacturer keeps control from bromination through separation, drying, and final bagging. This means product traceability—if a lot varies, our own records lead directly to its process run and raw material source.

    Downstream users frequently comment on the improvement they see when switching from brokered TBPA to ours: fewer batch rejects, cleaner melts, and more reliable test results for both mechanical and flame resistance. Our lab standards are based on years of collaboration with global resin manufacturers who hold us to rigorous requirements. For every lot, we check without exception for contaminated content and deviation from the declared particle size range. The feedback loop between production, QA, and client application labs means we adapt quickly, revising process conditions and documentation when the market or standards shift.

    Hazard And Environmental Considerations

    There’s no escaping the fact that brominated fire retardants face scrutiny from users, regulators, and communities alike. We view transparency with environmental and health data as a top priority. Each consignment leaves our facility with analytical results for halogen content, background levels of regulated impurities, and the presence of any volatiles or polycyclic organics.

    Our environmental team monitors waste streams closely, recovers as many process solvents as possible, and routs unwanted side products to approved outlets for safe treatment. We’ve moved to closed handling systems, both to protect our technicians from dust exposure and to ensure local air and water emissions stay far below national standards. TBPA does not include dioxin or furan precursors, and testing shows that its combustion byproducts fall well within regulatory thresholds for brominated emissions. This data isn’t just for compliance—it lets our partners generate cleaner safety records and maintain confidence in the finished goods they ship worldwide.

    Supporting Industry Progress With TBPA

    We remain close to the groups driving new standards in flame retardancy, from international building codes to the committees defining electronic device safety. TBPA enables the use of lightweight, high-strength resins in applications that earlier generations avoided for fear of fire risk or regulatory noncompliance. Our close work with automotive and aerospace suppliers has demonstrated that TBPA’s stability and high bromine efficiency support advanced molding and extrusion demands, especially as engine temperatures and electrification increase the need for robust, built-in safety in every part and assembly.

    Compatibility with glass-reinforced, mineral-filled, and specialty resins continues to extend TBPA’s uses, including more complex three-dimensional parts and thinner, lighter components. This helps the industry shift further from metal toward durable engineering polymers, benefiting design flexibility and fuel efficiency.

    Why Sourcing Directly From Us Makes A Difference

    It’s easy to overlook the impact of source when buying specialty chemicals. Traders and brokers contribute to wider market access, but the manufacturer owns the details: the minute adjustments in reaction flow, the checks for upstream impurities, and the responsibility for regulatory documentation. Being the source means we address problems immediately and have the technical depth to innovate or troubleshoot before issues leave the plant.

    Wherever clients use TBPA, we deliver more than powder: process data, application support, and a track record of adjusting to new regulations and customer innovations. We continuously update our process based on customer feedback, third-party test requirements, and changes in physical property demands. Our commitment goes further than just meeting current specs—we anticipate and develop for next-generation flame retardant composites, adapting TBPA for greener, more efficient material strategies.

    TBPA In The Moving Landscape Of Flame Retardancy

    Fire safety regulations keep evolving, and global supply chains place new pressure on quality and sustainability. In every sector we serve, downstream users want clarity on what their inputs contribute to product safety and performance. Our position as both manufacturer and research partner puts us in the room with regulators, code writers, and end-users, so we don’t just react—we help set the agenda for future materials.

    TBPA continues to adapt alongside stricter emission goals, moves toward more transparent supply chains, and growing environmental disclosure requirements. Because we’ve retained full process control, we can adjust specifications and provide material provenance at a level not possible in distributor-driven models. This builds confidence not only within the immediate buyer base but across the broader network of processors, molders, and brand owners relying on predictable, high-quality flame retardant performance.

    Customer Collaboration Drives TBPA Forward

    Our largest clients often approach with both tough specifications and tight timelines for supply and regulatory tests. By developing TBPA production in house, we shorten the loop from formulation idea to pilot lot. Our ability to generate custom documentation and rapidly sample different lot variants gives product development teams an edge—especially when qualifying new materials or responding to audit requirements.

    We actively invite feedback on both technical and operational fronts. This collaboration leads to better flow in production at our site, fewer rejected batches for the client, and improved performance metrics in independent testing labs. Our technical specialists share practical advice, not just theoretical knowledge; if a compatibility issue or melt index shift arises, we troubleshoot together.

    Our dedication to continuous improvement means we aren’t satisfied with legacy formulas. We test incremental changes under real production conditions, measure them against client requirements, and only release if improvements in handling, safety, or performance are demonstrated. These advancements end up in the next lot that leaves our site.

    Looking To What Comes Next For TBPA

    Market and regulatory uncertainty put pressure on manufacturers to balance cost, performance, and compliance. We’ve invested in smarter process controls, from feedstock quality monitoring to advanced end-point detection and recycling, each improvement echoing back in product consistency and reliability. Because local and global environmental laws never stop changing, our team continually reviews and updates MSDS sheets, technical dossiers, and application-specific safety guides in step with current best practices.

    Brominated flame retardants will keep playing a role in diverse energy, mobility, and infrastructure sectors. Within this evolving context, TBPA’s unique chemical and physical profile positions it to support the next wave of polymer innovation—lighter cars, smarter appliances, and greener construction materials that meet both modern performance and compliance standards.

    The Manufacturer’s Commitment

    Every batch of TBPA reflects the accumulated knowledge and skill of the people actually making the product. The difference this brings shows up in the field—higher pass rates, more satisfied customers, and a safer footprint for every finished part. Our responsibility does not end at the loading dock. We keep listening, refining, and updating based on hands-on use, regulatory trends, and the real pressures operators face. This cycle of engagement and improvement forms the foundation for long-term partnerships and genuine progress in fire safety chemistry.

    Those who need more than just a commodity ingredient recognize the value of deep expertise and transparent process control. As the direct manufacturer, we stand behind every kilogram of TBPA delivered—to support end users, safeguard communities, and help advance the sustainability and safety goals shared across today’s industries.