Yudu County, Ganzhou, Jiangxi, China sales3@liwei-chem.com 748718781@qq.com
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Phosgene

    • Product Name Phosgene
    • Chemical Name (IUPAC) carbonyl dichloride
    • CAS No. 75-44-5
    • Chemical Formula COCl2
    • Form/Physical State Compressed/Liquefied Gas
    • Factory Site Yudu County, Ganzhou, Jiangxi, China
    • Price Inquiry sales3@liwei-chem.com
    • Manufacturer Anhui Liwei Chemical Co., Limited
    • CONTACT NOW
    Specifications

    HS Code

    745976

    Chemicalname Phosgene
    Chemicalformula COCl2
    Molarmass 98.92 g/mol
    Casnumber 75-44-5
    Appearance Colorless gas
    Odor Musty, suffocating (similar to freshly cut hay or grass)
    Boilingpoint 8.3 °C (46.9 °F)
    Meltingpoint -118 °C (-180 °F)
    Density 4.42 g/L (at 0 °C, 1 atm)
    Solubilityinwater Slightly soluble (reaction produces hydrochloric acid and carbon dioxide)
    Vaporpressure 1120 mmHg (at 20 °C)
    Flashpoint Non-flammable
    Unnumber 1076
    Hazardclass 6.1 (Toxic substance)

    As an accredited Phosgene factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.

    Packing & Storage
    Packing Phosgene is packaged in 61-liter steel cylinders, painted gray with a yellow band, prominently labeled "Phosgene, Toxic Gas."
    Container Loading (20′ FCL) Container Loading (20′ FCL) for Phosgene: Transported in special steel cylinders, max. 20′ container holds approximately 12 metric tons under strict safety regulations.
    Shipping Phosgene is shipped in specially designed, tightly sealed steel cylinders under high pressure to prevent leaks. It must be clearly labeled as toxic and hazardous, complying with international transport regulations. During transit, it requires careful handling, proper ventilation, and emergency response measures due to its highly toxic and corrosive nature.
    Storage Phosgene should be stored in tightly sealed, corrosion-resistant steel cylinders or containers kept in a cool, dry, and well-ventilated area away from heat, direct sunlight, moisture, and incompatible substances such as water, amines, and bases. Storage areas must be clearly labeled, equipped with proper ventilation, and access restricted to specially trained personnel wearing appropriate protective equipment.
    Shelf Life Phosgene has an indefinite shelf life when stored in tightly sealed, corrosion-resistant containers under cool, dry, and well-ventilated conditions.
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    Tel: +8615365186327

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    Certification & Compliance
    More Introduction

    Phosgene: Insights from Our Manufacturing Floor

    A Straightforward View on an Essential Chemical

    Making phosgene every day leaves little room for vague talk or roundabout phrasing. In our plant, phosgene starts as a carefully controlled reaction between carbon monoxide and chlorine gas. Through years of practical experience, we’ve learned that the smallest inconsistencies in feed gas purity or temperature can change the outcome faster than math on paper lets on. As a tight, colorless gas with a distinct, penetrating odor, phosgene ranks among the most unforgiving chemicals we handle, both for safety and for consistency. Our production model uses high-grade carbon monoxide and chlorine, routed through corrosion-resistant reactors equipped with real-time sensors, allowing us to constantly monitor purity and pressure fluctuations.

    Our output delivers phosgene at a minimum purity of 99.8%, with batch records showing trace level impurities below standard detection. This level of purity isn’t just about operating in compliance; it clears the way for downstream syntheses, whether we’re talking about polycarbonate resins, isocyanates, or specialty agrochemicals. Small changes in impurity profiles can lead to inconsistent polymer grades or catalyst poisoning—something no downstream customer can afford to risk. Unlike some producers cutting corners with less precise process controls or questionable sourcing of raw gases, our decades-long focus never strays from real gas-phase efficiency and containment.

    Why Phosgene Remains Practical in Modern Synthesis

    Many outside the industry picture phosgene as a chemical best left in history books. On our side, its role in the daily manufacturing of plastics and pharmaceuticals remains broadly misunderstood. The rigid carbonyl chloride bond in phosgene reacts cleanly with amines, phenols, and alcohols, enabling the formation of carbamates, polycarbonates, and chloroformates. Some alternative approaches often get promoted as “greener,” yet few offer the same atom efficiency or selective reactivity. We track the scientific literature, and very few substitutes scale up with phosgene’s speed and atom economy.

    Demand for engineered plastics and isocyanate-based foams keeps climbing, not falling. Every day, design engineers still rely on polycarbonates for strength and transparency in impact-resistant applications, from aerospace windows to medical devices. Phosgene’s unmatched reactivity profile ensures we meet the molecular weights and clarity targets engineers specify, batch after batch. Urethane foam insulation, vital for energy efficiency and appliance performance, stays tied to our output. Throughout this chain, the need for a precise feedstock never lets up.

    How Our Production Standards Secure Consistent Quality

    To make phosgene work reliably as an upstream chemical, you don’t just buy reactors off the shelf. Our equipment specification came together over years of hands-on improvements: from coolers designed for rapid temperature drop, to inline scrubbers capturing trace chlorine, to robust emergency venting. We install triple-redundant sensors along every line to ensure there’s never an unscheduled deviation above safe thresholds. Gas-tight seals, frequent line inspection, and round-the-clock operator training fill the gaps no automatic system covers. We know from real incidents that trusting only automation tempts fate.

    Alongside strict technical measures, we run production logs with operator signatures, timestamped gas analysis, and real-time feedback from in-house labs. This habit catches small faults before they turn into process drift. Any aberration in color, odor, or condensation pattern prompts a shutdown and review. Our own staff reports every minor leak or backpressure event, and we act on each report. The result: day after day, the plant meets the same GC-MSD profile, showing no detectable variances in the phosgene product.

    From Laboratory Practices to Industrial Scale

    Many lab protocols look theoretically sound but buckle when translation begins in full-sized plants. In making phosgene, temperature slope, flow rates, and mixing must match real-world volumes, or the product slips out of specification. Even differences in chloride source or atmospheric humidity challenge even the most well-regarded bench protocols. In our experience, scale brings unique hurdles: corrosion rates accelerate, byproduct formation increases, and risk to personnel rises. We learned early on that small pilot units sometimes mislead about heat transfer and agitation adequacy; plant-scale gas flow demands custom design, grounded in field measurements, not simulations alone.

    As we scale, transport adds challenges. Phosgene moving from reactor to cylinders gets monitored for pressure, valve integrity, and double redundancy in shut-off systems. Each drum passing into transport undergoes weight checks, leak detection, and container surface inspection. Problems that seem rare—like frost line formation on container heads—forced us into continuous improvement loops, updating both procedures and hardware. We revise our transport standards with each new incident or technical paper, no matter how minor. Sticking to off-the-shelf logistics never paid off for us or our end users.

    Understanding Uses and Demands on Purity

    Several application routes push us to keep specifications tight. In polycarbonate synthesis, phosgene serves as the carbonyl donor, reacting with bisphenol A in nonaqueous conditions. Reactivity must align with batch timing; too slow and side products multiply, too fast and runaway hazards appear. Catalyst poisoning by trace old chlorine remains a frequent pitfall in this field—the reason we double-filter and track outgassing parameters on every run.

    Phosgene also drives isocyanate production, a critical link in the polyurethanes supply chain. Here, presence of moisture or sulfide impurities stalls reaction rates and degrades quality, potentially leading to off-spec foam or downstream performance failures. Even in seemingly simple tasks, like producing chloroformates for pharmaceutical intermediates, phosgene’s reactivity serves up highly pure end products—only if the starting material matches the tight standards developed from years at the reactor.

    Comparing Phosgene to Alternative Chemicals

    Some industrial processors now promote triphosgene or diphosgene, both solid at room temperature, as “safer” alternatives due to easier handling. Having tested these variants, direct experience showed us such chemicals often trade away speed and reactivity. Even with specialized reactors, we found batch times climb, side-product removal toughens, and product yields rarely match those from gas-phase phosgene. For manufacturers running continuous or high-volume operations, these issues add cost and time, which few downstream plants welcome.

    Alternative carbonylation agents in research facilities show promise, but at scale, most falter on cost or waste treatment. The in-plant reality: phosgene leaves minimal residual salts, and its volatility lets us recover and recycle more efficiently than most non-gaseous options. Even with the demands of modern safety culture and regulatory compliance, phosgene holds its place—no less dangerous, but no less practical.

    People and Safety: Direct Experience Over Theory

    No matter how long we run phosgene reactors, a healthy respect stays in force across the team. Every operator—from senior engineer to rookie shift apprentice—knows the incident history, both globally and in our own walls. Regular training refreshes never turn into box-ticking exercises. We bring in case studies of historical accidents, analyze each root cause, and redesign procedures accordingly. For us, incident mitigation starts with prediction, not just reaction.

    On the safety technology side, our team developed custom real-time leak detectors, positioned along both loading bays and walkways into the packing house. The sensors link with the local emergency response, locking down systems at the faintest unplanned release. Safety drills run through escape routes, with documented time trials and after-action notes revised after every session. In daily routines, watches pick up even minor corrosion or gasket swelling, prompting immediate investigation. No standard operating procedure stays static; field lessons shape weekly updates, agreed on in team briefings, not handed down from distant policy teams.

    Advancements and Future Trends

    Technological upgrades change faster now than in the past. Automation in monitoring and batch correction cuts small errors before they snowball. Our maintenance schedule matches or outpaces changes in equipment, adding new sensors or replacing heat exchangers before cracks even hint at fault. Process modeling and digital twins let us run virtual batches ahead of plant changes, reducing real-world trial and error. These changes don’t remove the need for practical, eyes-on experience; they reinforce our plant culture by letting humans focus on what machines can miss: intuition built on familiarity.

    We keep up with international regulatory changes, tuning our process not just to local guidelines, but to stricter export markets. Inspection protocols turn stricter with every revision, incorporating lessons from multinational safety networks and chemical exchange groups. Throughout these changes, our top priority remains constant: delivering pure phosgene, meeting the tight timelines manufacturers demand, without exception or compromise.

    Supporting Innovation from the Ground Up

    Innovation in phosgene use shapes the next generation of materials and pharmaceuticals. We support R&D units needing pilot-scale phosgene, not only for contractual supply but for open technical exchange. Having seen countless research programs falter at scale-up, we work with clients to troubleshoot reactor design, purge protocols, or byproduct collection. Open communication—in which nothing gets sugar-coated—helps resolve both anticipated and unexpected challenges. We know the pitfalls that bench researchers may miss, and we share honest feedback, even if it challenges assumptions or changes project timelines.

    The boundaries of phosgene chemistry expand yearly, with new applications in high-density data storage, improved agrochemical intermediates, and out-of-the-box polymers for medical uses. Tracking these trends calls for far more than a glance at headlines; it takes a seat at the table with engineers, scientists, and operators balancing ambition with realism. Our ongoing participation in international chemical forums and standard-setting bodies helps us both anticipate market shifts and refine our own processes before regulation catches up.

    Supply Chain Realities and Solutions

    The modern supply chain poses real challenges, especially for a substance as tightly controlled and hazardous as phosgene. International shipment means rigid scheduling, in-transit tracking, and pre-clearance at every dock and port. Our team manages these hurdles through pre-shipment communication with all receiving parties, direct engagement with local authorities, and electronic logs tracking every handoff. Not having a link in the chain tightly managed leaves an opening for mishaps, so direct responsibility always stays with our in-house staff—not third-party brokers.

    Regional plant shutdowns, weather disruptions, and transportation logistics create unplanned challenges every year. To mitigate these, we split production across multi-location storage hubs, buffer regional inventories, and run simulation-based scheduling to spot pinch-points before orders go short. A detailed risk register, maintained weekly, lists every possible disruption, matching contingency protocols for each. These efforts keep us at the forefront of reliable supply, one shipment at a time.

    Transparency and Environmental Responsibility

    Phosgene manufacturing comes with a real environmental footprint. Unlike less hazardous chemicals, we cannot cut corners on containment or byproduct capture. Our plant air and water emissions stay stringently below both statutory and self-imposed thresholds, with third-party audits checking compliance. Regular scrubber upgrades, leak-proof containers, and on-site neutralization stations shape our invested commitment. We explain these measures clearly in every audit, not because oversight demands it, but because credibility grows only from visible example.

    To us, responsible phosgene production rests on two legs: technical excellence and public trust. This includes prompt, complete incident reporting, openness with surrounding communities, and regular briefings with environmental and occupational health teams. Arms-length assurance does not satisfy our culture or customers; direct engagement always yields the best improvements, both in plant safety and environmental stewardship.

    Direct Support for Manufacturers and Researchers

    We started as end-users before building out production. This background lets us anticipate the daily questions and pressure points our customers face. Our team provides actionable solutions—such as optimizing reactor inlet ratios or specifying transfer lines—based on factual data drawn from years on the ground. We do not shy away from candid conversations about challenges, cost structures, or real risk assessment. Solving customer problems before they reach crisis level keeps relationships productive and long-standing.

    Support extends to R&D partners needing scalable solutions for new reactions or applications. Whether troubleshooting downstream fouling, scaling pressure loads, or adapting for regulatory compliance, our advice draws from in-plant trials and real batch data. We keep our communication open: if something can be made safer or more efficient, we provide working examples and reliable contacts—not just manual excerpts.

    Informed Choices Matter More Than Ever

    Phosgene stands as a chemical that rewards precision, diligence, and integrity. In a field with little margin for error, shortcuts find out even the most advanced operators. Our practical experience, close collaboration with customers, and commitment to continuous improvement keep us moving forward. The chemical industry rests on trust in process, reliability in delivery, and willingness to discuss hard truths. We invest in every shipment, every innovation, and every partnership with these principles.

    Those looking to incorporate phosgene benefit from choosing a supplier whose staff knows the product from every angle—from theoretical yield to hands-on, shift-by-shift stewardship. Our direct feedback from decades on the plant floor shapes every decision, every improvement, and every assurance we give. For those ready to advance their manufacturing with the best available phosgene, we’re ready—open, realistic, and fully accountable every step of the way.