|
HS Code |
117075 |
| Cas Number | 124-09-4 |
| Molecular Formula | C6H16N2 |
| Molar Mass | 116.21 g/mol |
| Appearance | Colorless to pale yellow liquid or crystalline solid |
| Odor | Ammonia-like |
| Melting Point | 39–42°C |
| Boiling Point | 204°C |
| Density | 0.84 g/cm³ at 20°C |
| Solubility In Water | Miscible |
| Flash Point | 87°C (closed cup) |
| Ph | Alkaline, typically >11 (for aqueous solutions) |
| Vapor Pressure | 0.31 hPa at 20°C |
As an accredited Hexamethylenediamine factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | Hexamethylenediamine is packaged in a 200-liter blue HDPE drum, tightly sealed and clearly labeled with hazard warnings and handling instructions. |
| Container Loading (20′ FCL) | Hexamethylenediamine is loaded into 20′ FCL containers using drums or IBCs, ensuring secure, sealed, and compliant chemical transport. |
| Shipping | Hexamethylenediamine is shipped as a hazardous material, typically in tightly sealed drums or containers made of compatible materials to prevent leaks. It should be kept away from acids and moisture, and transported according to regulations for corrosive substances, with appropriate hazard labeling and documentation for safe handling during transit. |
| Storage | Hexamethylenediamine should be stored in a cool, dry, and well-ventilated area, away from sources of ignition. Keep containers tightly closed and protected from moisture and direct sunlight. Store separately from acids, oxidizing agents, and other incompatible materials. Use corrosion-resistant containers, and ensure the area is equipped with appropriate spill containment and safety measures. Proper labeling and access restriction are essential. |
| Shelf Life | Hexamethylenediamine typically has a shelf life of 2 years when stored tightly sealed in a cool, dry, and ventilated area. |
Competitive Hexamethylenediamine prices that fit your budget—flexible terms and customized quotes for every order.
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Tel: +8615365186327
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Hexamethylenediamine, or HMDA, plays a daily role in our operations. This colorless, water-miscible liquid with a sharp ammonia-like odor formed the foundation of our earliest production lines, and it remains a keystone product. Our focus has always been on delivering consistent quality—keeping every batch pure, with tight control on moisture, color, and residual ammonia content. Main production flows use the hydrogenation of adiponitrile as their core process. Over time, we've optimized several steps, refining purification methods, to ensure a stable product that consistently meets customer standards for reactivity and residue limits.
Our current HMDA output, available in multiple grades, includes an industrial-standard model that lays the groundwork for high-performance polyamides. This grade meets polymerization requirements for critical sectors and keeps free of contaminants that disrupt downstream synthesis. Whether customers require bulk rail shipments or drum quantities, the same dedication to purity, safety, and secure packaging runs through every order dispatched from our factories.
Polyamide-66 production owes its existence to hexamethylenediamine and adipic acid. The reaction of these two results in nylon 66, which forms the fibers behind textiles, tire cords, and engineering plastics. The scale of nylon 66 demand worldwide drives investment in quality HMDA—one wonky batch can result in millions in lost revenue across the supply chain. Consistency here isn’t just a catchphrase—it matters for melt-point, tensile properties, and fiber formation rates on high-speed lines.
Our direct involvement in nylon 66 value chains gives us a practical view of how every fluctuation in HMDA purity impacts the real world. During monomer charging and salt formation, off-spec diamine leads to yield loss and waste, whether in yarn, film, or molded part form. We design products to avoid this. Reliability, for us, comes from decades of process tuning, understanding subtle shades of color variation, or controlling amine impurities that trace back to raw material inconsistencies.
Hexamethylenediamine’s value goes well beyond polyamide-66. It provides the diamine backbone for a wide range of industrial resins, including epoxy hardeners, polyurethanes, lubricants, corrosion inhibitors, and water treatment chemicals. In each application, the challenge revolves around maximizing reactivity while controlling byproduct formation. For example, formulating an isocyanate-resistant urethane prepolymer needs tight control over diamine moisture and secondary amine content.
In our facilities, we collaborate with research teams and production users to tailor feedstock for adhesives and coatings. Each request—whether it’s for ultra-low color for optical resins or extra-low water for moisture-sensitive curing—receives direct attention at our quality labs. We don’t see “industrial” as “one-size-fits-all.” The real world demands precision. Slight edge in control means a broader operating window for our customers. In performance coatings, even trace residues from storage tanks can destroy shelf life or change film properties. Smarter bulk handling systems mean cleaner lines and lower contamination risks.
Direct day-to-day experience with HMDA shows that its physical properties matter for plant safety. This is not a benign material. It absorbs moisture, reacts with carbon dioxide, and can corrode many standard metals. The sharp odor signals volatility, and handling guidelines must be respected. From storage tank linings to pressure relief design, every facet of our HMDA operation got built through lessons learned—many, not from textbooks, but from dealing with real-world leaks, tank vents, and filters. Investing in inners of fluoropolymer lining or 316L stainless steel didn’t happen to satisfy theory—it prevents downtime and avoids batch contamination.
Our plant teams spent years refining drum-filling lines, moving from open filling to closed, nitrogen-blanketed systems. These changes stem from firsthand observation: a single unsealed drum picks up water and CO2 overnight, throwing the batch out of spec. Staff training sits at the core. We rely on operator experience with pump seals, mask types, and tank-cleaning protocols. Hexamethylenediamine vapor can be persistent in poorly ventilated areas. Returned, reused drums pose cross-contamination risks without rigorous cleaning. Our logistics teams consult records to track drum life cycles, and that added detail makes our product a safer, more reliable raw material for everyone downstream.
Many players offer HMDA on the global market. What we bring stems from vertical integration: we produce, process, and ship directly. Supply rarely encounters bottlenecks from intermediaries, and closer internal monitoring links every tank and warehouse to a quality manager who knows the stakes of a single off-spec shipment. Real traceability cannot come from a long chain of resellers—it grows when operators and lab techs know each tanker shipment will end up in medical devices, food-contact materials, or safety equipment.
We hold ourselves to high analytical standards—not just for basic amine value and water, but also for trace metals and organic residues. Regular audits pull out-of-spec tanks before they reach the pipeline. We maintain real-time process analytics that help us spot issues as they arise instead of waiting for end-of-batch checks to flag surprises. This hands-on vigilance supports recipes needing chromatic purity, or performance applications with minuscule tolerance for inconsistencies.
Customers shifting from other suppliers frequently mention fewer line stoppages, reduced filter blockages, and improved product yields as immediate results. We look at these as simple outcomes of focusing on actionable detail—something that’s only possible by owning and refining every step, from raw raw-stock hydrogen purification to final tank farming for bulk storage.
Our model selection reflects input straight from demanding users. For specialty fiber and compounding needs, we offer extra-low color and stabilized grades that help minimize discoloration in end products. Our in-house blends target sub-10 ppm moisture contents, and customized packaging delivers HMDA suitable for batch or continuous processes. This isn’t to “meet the market”—it came from years of troubleshooting user issues, from crystallization in pipes to color drift in masterbatch preparation.
Field engineers from our site work with client plants, observing how resin formation, extruder operation, and downstream blending respond to subtle HMDA batch differences. We saw that even the best theory cannot substitute for field feedback—thermal stability, amine volatility, and tank transfer all play out differently across climates and technologies. As manufacturing moved to higher-speed and lower-tolerance systems, we tightened controls on amine impurities—because lower impurity content supports longer production runs without fouling or polymer yellowing.
We currently supply material typically with hexamethylenediamine assay above 99.8%, less than 50 ppm water, clarity conforming to APHA standards, and impurity controls based on ongoing feedback. Purification is monitored 24/7. Each iteration in our facility’s technology evolved after user complaints or requests—there’s no shortcut for continuous dialog between users, plant staff, and QA teams. Packaging has moved from simple drums to tank containers and bulk ISO tanks, responding to upscaling in customer demand as well as a need for safer, more reliable delivery across climates.
Hexamethylenediamine stands out against typical diamines because of its chain flexibility and balance of reactivity and volatility. Shorter diamines (like ethylenediamine or butanediamine) often bring higher volatility, toxicity, or excessive plasticizing effects when used in polymer blends. These factors compromise final product strength or processing safety. Longer diamines, with greater chain length, will decrease rigidity in finished polyamides, resulting in softer polymers not suitable for structural applications.
From a synthetic chemist’s viewpoint, HMDA provides an ideal balance for condensation reactions leading to strong, thermal-resistant polymers. Process engineers routinely point out that downstream drying and handling of HMDA introduce less operational hazard and less negative effect on mechanical properties versus higher-volatility diamines. It brings high purity, manageable toxicity with robust controls, and compatibility with a vast range of polycondensation systems, without leaving excess unreacted amines or generating discoloration in white or transparent plastics.
For clients working with polyamides, especially nylon 66, the amine chain length in HMDA establishes the precise crystal packing needed for fiber strength and wear resistance. Deviating from this architecture results in marked decreases in melting point and durability, directly impacting everything from industrial yarns to electronic housings. We have visited processing facilities across the globe where switching to a shorter or longer diamine—but otherwise “similar” grades—has led to filter plugging or off-color final products. In this context, our hexamethylenediamine continues earning its role as the backbone for modern high-performance polyamides.
Investing in HMDA production involves continual balancing between yield, purity, and energy consumption. The hydrogenation of adiponitrile remains energy-intensive, with waste byproducts that require careful handling. Our teams have focused on improving hydrogen utilization and recycling side-process streams, cutting waste generation. Adiponitrile sourcing also links our operations to upstream petrochemical cycles, so we work alongside feedstock partners to stabilize supply and minimize knock-on effects of global oil volatility.
There are direct efforts underway to reduce process wastewaters and capture process off-gases. Our upgrades in stripping columns and distillation tech help each kilogram of finished product carry a lower environmental impact than a decade ago. As decarbonization pressures continue rising, we conduct ongoing reviews to minimize carbon footprint—these range from shifting plant utilities to cleaner sources, fine-tuning reactor residence times, and reusing process solvents rinsed from shipping tanks.
From a safety standpoint, handling large volumes of HMDA means always being alert to the risk of fugitive emissions and liquid spills. Everyone in our operations has seen how an unnoticed leak in a transfer pump or aging gasket leads to odor release and, sometimes, exposure events. We now use double-sealed pumps, continuous emission monitors, and rapid response systems to quickly locate and neutralize leaks. Our experience shows it’s one thing to check a box for regulatory compliance, and another to pursue practical plant safety that delivers for both staff and the communities living near production sites.
Years spent engaging with manufacturers across the textile, resin, and specialty chemical fields show us that strong relationships drive product evolution. Our approach focuses on real technical support—clients involved in scaling up or troubleshooting polymerization issues draw on both lab support and on-site troubleshooting. We host technical workshops and open plants for audits, not simply to tick procedural boxes, but because knowledge flow in both directions makes for safer and higher-performing products.
Clients working on advanced applications, such as lightweight car parts, high-performance membranes, or abrasion-resistant fiber blends, look for tighter impurity and moisture controls. We invest in R&D with their teams, chasing new catalysts or alternative feedstocks, because disruptive progress only comes from practical risk-taking. In some projects, tighter inline analytics have shortened client trial times, so they get new products to market faster with fewer failures and less waste.
The reality of running a large-scale HMDA operation involves embracing each batch as a test of standards. Feedback channels, from routine returns to comprehensive client audits, shape process tweaks and updates. R&D pushes us toward alternative routes for lower carbon feedstocks; site managers pursue incremental safety gains from years-long incident reviews. Our overall approach rests on vigilance and flexibility, because customer priorities, environmental rules, and performance requirements never hold still.
We don’t claim perfection—occasional quality deviations, transport delays, or packaging mishaps arise. What distinguishes our operation is the speed and depth of our response, and a culture that values long-term relationships over transactional success. Our staff drive improvements in process safety, waste recovery, and product stability by focusing on field data, not just spreadsheet analysis.
As customers develop new markets for advanced resins, coatings, and specialty polymers, they need suppliers who connect technical, regulatory, and logistical insights. Our confidence in serving this need comes from direct production experience—every step, from synthesis to packaging to technical troubleshooting, happens under our own roof and with our own oversight.
Looking ahead, HMDA will remain a linchpin for synthetic materials, but the world’s expectations are shifting. The drive for lower carbon footprints, safer raw materials, and renewable feedstocks compels us to push beyond today’s processes. We are exploring alternative hydrogen and adiponitrile sources with partners, revising purification systems, and modifying supply logistics to reduce the overall environmental burden. Each improvement is measured in tangible benefits: less waste, safer work, fewer off-spec shipments, and new openings for customers eager to push their own innovation.
Decades of manufacturing experience with hexamethylenediamine gives us a clear perspective on what works and what struggles in the real world. Customers continue counting on reliable supply, technical expertise, and tailored support for both legacy and emerging applications. By blending hands-on production insight with ongoing research and technical collaboration, we keep our place at the leading edge—empowering our customers to drive growth across sectors that depend on secure, high-purity, and responsibly made HMDA.