|
HS Code |
301822 |
| Cas Number | 88-44-8 |
| Molecular Formula | C7H9NO3S |
| Molecular Weight | 187.22 g/mol |
| Synonyms | 4-Amino-2-methylbenzenesulfonic acid; 4-Amino-m-toluenesulfonic acid |
| Appearance | White to light beige crystalline powder |
| Melting Point | 190-194°C (decomposes) |
| Solubility In Water | Soluble |
| Purity | Typically ≥98% |
| Ph 1 Solution | Approx. 2.0-3.0 |
| Application | Intermediate for azo dyes and pigments |
| Odor | Odorless |
| Storage Conditions | Store in a cool, dry place, protected from light |
As an accredited 4B Acid(4-Aminotoluene-3-Sulfonic Acid) factory, we enforce strict quality protocols—every batch undergoes rigorous testing to ensure consistent efficacy and safety standards.
| Packing | The packaging for 4B Acid (4-Aminotoluene-3-Sulfonic Acid) contains 25 kg, sealed in a sturdy, labeled fiber drum. |
| Container Loading (20′ FCL) | Container Loading (20′ FCL) for 4B Acid (4-Aminotoluene-3-Sulfonic Acid): Typically 16–18 metric tons packed in 25kg bags. |
| Shipping | **Shipping Description for 4B Acid (4-Aminotoluene-3-Sulfonic Acid):** Ship in tightly sealed containers, protected from moisture and incompatible substances. Classify as a non-hazardous material unless specified otherwise by local regulations. Store in a cool, dry place, away from direct sunlight. Handle with gloves and eye protection to avoid contact during transport and unloading. |
| Storage | 4B Acid (4-Aminotoluene-3-Sulfonic Acid) should be stored in a tightly closed container, in a cool, dry, and well-ventilated area away from incompatible substances such as strong oxidizers. Protect it from moisture and direct sunlight. Ensure the storage area is equipped to contain spills and that appropriate personal protective equipment is available when handling the chemical. |
| Shelf Life | 4B Acid (4-Aminotoluene-3-Sulfonic Acid) typically has a shelf life of 2 years if stored in cool, dry conditions. |
Competitive 4B Acid(4-Aminotoluene-3-Sulfonic Acid) prices that fit your budget—flexible terms and customized quotes for every order.
For samples, pricing, or more information, please call us at +8615365186327 or mail to sales3@liwei-chem.com.
We will respond to you as soon as possible.
Tel: +8615365186327
Email: sales3@liwei-chem.com
Flexible payment, competitive price, premium service - Inquire now!
Decades in the chemical industry shape how we approach both the science and the business. Manufacturing 4B Acid—known among specialists as 4-Aminotoluene-3-Sulfonic Acid—has challenged us, inspired upgrades in our plant, and built bridges to industries that demand unwavering consistency. We realize that even subtle variations in this product can affect the cost and reliability of the dyes and chemicals built on its backbone. Our years of overseeing every bag and drum leaving the factory floor have shown the real-world impact of those nuances—product stability doesn’t just matter, it translates directly into the performance and color quality that downstream users demand.
In our process, every batch of 4B Acid reflects accumulated knowledge and practical improvements. We source raw materials only from vetted mines and refineries with established quality records. Years ago, we struggled with fluctuations in para-toluidine purity, but after overhauling our supply chain and testing methods, we've reached the point where material consistency is controlled from the very first step.
Our reactors operate at carefully monitored temperatures and pressures. We track sulfonation rates daily. The finished product emerges as a stable white to off-white powder, and our in-house lab confirms identity by melting range and validated chromatographic fingerprinting, not just a quick color test. We choose granular or fine powder grades based on feedback and actual performance in dyehouses—not just to widen a catalog, but because several industries asked for it and followed through with bulk orders. For those who use large batches, we’ve invested in dust-suppressed handling and bagging lines to improve ergonomics and reduce airborne particles on the packing floor.
This molecule, officially described as 4-methyl-2-aminobenzenesulfonic acid in chemical registries, starts its journey in our reactors with a sulfonated methyl group on aniline’s benzene ring. Specialists in azo dye manufacture recognize it immediately as a critical intermediate, essential for preparing several red and violet dyestuffs. The amino group allows for straightforward diazotization, giving formulators a dependable route toward coupling with various components to yield strong, reproducible shades. This is not an ornamental part of the process—minor impurities or inconsistent melting points can disrupt synthesis paths, increase waste, and add raw-material costs.
For textile dye users, what matters most is whether their color recipes yield the same shade, batch after batch. Several domestic and overseas customers have traced color drift back to inconsistent intermediates, not faulty batch mixing. Over years of troubleshooting, we have adjusted our process so the sulfonic acid content floats within a very tight band—protecting the bright tones and reducing reprocessing.
We supply 4B Acid in grades tailored by feedback from partners working in dyes, optical brighteners, and electronic chemicals. Some downstream users demand ultra-low iron content, since even trace metals catalyze side reactions in high-value dye syntheses. In our plant, filtration systems capture fines and metals longer than basic sediment removal. Extensive analytical screening with ICP-OES for elemental purity ensures each lot meets—or typically exceeds—the criteria those users require.
Color quenching and chroma stability present practical problems in dye manufacture. If residual by-products from incomplete sulfonation slip through, a pigment producer will lose hours and raw materials chasing uneven or dull colors. Several years ago, a large customer in South Asia demonstrated, through blind testing, that our production yielded the lowest visible haze and most consistent dye-bath outcomes, which turned into a long-term contract. We believe in letting plant managers and chemists try actual production runs—that's the only reliable way for them to see these differences for themselves.
Plenty of sulfonated aromatic amines populate catalogs, and some buyers ask about similarity and interchangeability. But our experience highlights a stubborn fact: even minor changes to the molecule, like swapping the methyl group’s position or amine’s location, can disrupt dye performance. For example, shifting from 4B Acid to its more common cousin, 2B Acid (4-Aminobenzenesulfonic acid), produces different coupling speeds and color positions. That substitution doesn’t save money if the final color goes off-spec or yields drop below 90%.
Another common question—why not use cheaper, fully synthetic intermediates imported from regions with relaxed quality norms? Over the years, we’ve seen the price advantages of these sources evaporate once factories contend with fouled batches, customer returns, or regulators noticing higher discharge of unreacted aromatics in wastewater. High-integrity 4B Acid translates into less effluent complexity for users, not just better yields.
Working with strong acids and aromatic amines at once brings its own set of factory-floor hazards. We’re frank about this: the aromatic structure gives off a faint odor on open handling, and workers require both suitable PPE and prompt washing stations. While our factory has made design changes—like negative pressure extraction and local airflow controls—the goal is to protect both people and the ambient environment. Frequent training and drills remain part of daily routines, and our safety records show a downward trend in minor incidents over the past decade. Any plant considering regular 4B Acid usage should evaluate safeguards and local extract ventilation. Off the shelf PPE is not enough for repeated, high-volume exposures; we recommend heat- and acid-resistant gloves and face protection, since even a small splash of the powder or solution can be an irritant.
Dust mitigation is another topic that often arises. Our granulated product flows well and rarely cakes, but in humid regions, even this grade benefits from sealed storage and periodic checks for moisture ingress. We work directly with warehouse managers to fine-tune bagging and stacking routines, because minimizing clumping translates into fewer weighing and metering headaches later on.
Over the last several years, industrial standards around sulfonated amines have shifted. Environmental regulators ask tough questions about effluent, waste heat, and potential carcinogenic byproducts. We responded by switching to closed-loop reactors, acid scavenging, and on-site treatment to catch organics that previous generations of technology vented to air or water. We didn’t adopt these upgrades solely for compliance, but because downstream users now get asked about the cradle-to-gate impacts of their chemical supply.
Registries for textile processing, leather finishing, and paper manufacturing all audit for heavy metals and persistent organics. Our experience shows that clients trusting their supply chain—down to the level of the actual intermediate supplier—enjoy fewer regulatory interruptions than those who buy sight-unseen from traders or miscoded imports. Beyond local laws, several brands now want documentation covering everything from water usage to air emissions. It’s not just paperwork: one global customer required specific disclosures before renewing a multiyear supply contract.
Several customers over the years have faced scale-up headaches: as orders grew, old problems with batch uniformity reappeared, and dust or clumping led to inaccurate metering. Our technical teams responded by adjusting not just product form, but also storage advice and loading equipment recommendations. The small cost of proper screw-feed hoppers or lined bins pays off by slicing downtime and minimizing product waste.
One challenge less discussed among end users—compatibility among intermediates. Some dyehouses switch between 2B and 4B Acid depending on pricing, only to struggle with longer set times or slight color shifts no one anticipated. We work with those buyers to chart out, side-by-side, what process parameters need adjusting to ensure minimal disruption. Manufacturers who use only certified, high-purity 4B Acid as their standard report far fewer out-of-spec color batches.
Every product we send out reflects not just what’s possible on paper, but what survives the demands of scale, storage, and years of manufacturing. Several R&D teams at major dye companies have visited our site specifically to observe QA routines and reactor design. We welcome these visits—they encourage both transparency and lifelong improvements to process control.
Practical lessons from these collaborations feed back into how we train staff and update process control recipes. Real-life issues, like minute pH drift during sulfonation, revealed themselves only after years of hands-on learning. We caught those quirks because our team dug deeply into feedback about final color accuracy and the solubility of downstream dyes. Theoretical specs cannot substitute for seeing which drums show up on a customer’s dock in flawless condition.
Ongoing research also addresses the demands of new, environmentally responsible dye formulations. Several big accounts now ask for routine screening beyond legacy impurities—such as nitrosamine precursors or microplastics from packaging. We responded by investing in both better lab testing and alternative packaging where high temperatures or humidity threaten standard bags. Our long-term collaborations with university chemists and regulatory specialists drive these upgrades, and we welcome their audits and data requests as part of continuous improvement.
As demand for quality dyes and specialty chemicals grows, 4B Acid continues to earn its spot as a cornerstone intermediate. Customer feedback and market data both suggest that projects relying on generic or off-grade intermediates bog down more often, whether from rejected lots, material waste, or unexpected downtime. Decades in the field have proven the importance of consistent raw materials. Conversations with procurement managers, R&D staff, and factory operators affirm the same point: trust and reliability in basic inputs fuel the rest of the supply chain.
We stay in touch with large users and small customers alike, listening to both so new requirements or tweaks to processes never get overlooked or lost in committee. That hands-on approach grounds our long-term commitment to producing not just any 4B Acid, but the version our partners expect—every drum, every bag, every year.
Our direct relationships with users go beyond selling product. We guide new clients through safe handling, process integration, and troubleshooting. Many plants that switched from generic supplies to ours report smoother start-up curves and faster stabilization of their dye-bath runs. Those who integrate 4B Acid into electronic chemical syntheses value this product for a well-established analytical profile and minimal variability. Over time, we have built up libraries of Q&A and real incident logs, so any new challenge—be it with temperature management, purity questions, or reason for counterion build-up—draws on hard-won experience, not theory.
We invite prospective partners to review our technical documentation, discuss unique requirements, and, if needed, tour our facilities. The point is not to dazzle with presentation but to provide confidence in the actual processes, real results, and practical knowledge that underpin every shipment we make.
Producing 4B Acid as actual manufacturers shapes everything we do—from the sourcing of each raw material to the guidance we offer end users. The chemical isn’t a commodity for us; it's a product defined by daily effort, accumulated experience, and ongoing partnerships with industry leaders who depend on ultimate reliability in their formulations. Our plant, our team, and our product all reflect that real-world commitment. We intend to keep it that way as the industry moves forward.