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Material Safety Data Sheet (MSDS) - Polybutylene Terephthalate (PBT)

Identification

Product Name: Polybutylene Terephthalate  Chemical Formula: (C12H12O4)n  Synonyms: PBT, Thermoplastic Polyester  Usage: Components for electrical, automotive, and consumer products  Manufacturer Contact: Refer to product label for supplier details  Emergency Contact: Local Poison Control Center or company emergency number

Hazard Identification

Physical State: Solid (pellets, granules)  GHS Classification: Not classified as hazardous according to GHS  Route of Exposure: Dust inhalation, eye contact, skin contact during processing  Health Risks: Dust may irritate eyes and respiratory tract, molten polymer can cause severe burns  Environmental Risks: Not readily biodegradable, potential harm if released in waterways

Composition / Information on Ingredients

Chemical Identity: Polybutylene Terephthalate Polymer  CAS Number: 24968-12-5  Ingredient Breakdown: Polybutylene Terephthalate (>90%), inert additives and colorants (<10%) by weight  Impurities: No significant hazardous impurities identified under normal processing

First Aid Measures

Eye Contact: Rinse eyes with water for 15 minutes, keep eyelids apart, access medical attention if irritation persists  Skin Contact (Solid): Wash with soap and water  Skin Contact (Molten): Cool area immediately with water, do not peel polymer off skin, seek urgent medical help  Inhalation: Move affected person to fresh air, seek help if breathing difficulties arise  Ingestion: Rinse mouth, obtain medical advice if large amounts are swallowed

Fire-Fighting Measures

Extinguishing Methods: Use foam, dry chemical powder, carbon dioxide, water fog  Hazards from Fire: Combustion may release hazardous vapors, including carbon monoxide, carbon dioxide, formaldehyde  Protective Equipment: Firefighters need full protective gear and self-contained breathing equipment  Special Considerations: Cool nearby containers with water to prevent heat damage, avoid inhaling fumes

Accidental Release Measures

Personal Protection: Wear safety goggles, gloves, and dust masks if handling spilled granules or dust  Environmental Precautions: Prevent entry of spilled pellets or dust into drains or natural water systems  Spill Cleanup: Sweep or vacuum up material, place in marked container for recycling or disposal, wash down residue avoiding excessive water flow

Handling and Storage

Handling Recommendations: Ensure adequate ventilation at workstation, use methods to control dust  Storage Conditions: Store in dry, cool, well-ventilated area, keep bags or containers tightly sealed  Incompatible Materials: Avoid contact with strong oxidizing agents  Special Instructions: Disconnect sources of static electricity, store away from heat and moisture

Exposure Controls and Personal Protection

Occupational Exposure Limits: No specific OSHA or ACGIH limits for PBT, control dust below nuisance threshold (typically 10 mg/m³ for total dust)  Engineering Controls: Use local exhaust ventilation at process points, maintain good general room ventilation  Personal Protective Equipment: Wear safety glasses, gloves, long sleeves, and use respiratory protection in dusty environments  Hygiene Measures: Wash hands after handling, do not eat, drink, or smoke during use, change contaminated clothing promptly

Physical and Chemical Properties

Appearance: White or off-white granular, pellet, or powder form  Odor: Faint, aromatic or neutral  Melting Point: 220-225°C  Boiling Point: Not applicable  Decomposition Temperature: Above 280°C (emits fumes)  Solubility (Water): Insoluble  Specific Gravity: 1.3  Flash Point: >400°C  Vapor Pressure: Not relevant at workplace temperatures  pH: Not relevant (solid polymer form)  Other Properties: Stable under standard storage, low flammability in ambient conditions

Stability and Reactivity

Chemical Stability: Stable in ambient atmosphere and recommended storage  Incompatibilities: Strong acids, alkalis, oxidizing materials  Hazardous Decomposition: Fumes may contain carbon oxides, hydrocarbons, and trace formaldehyde on decomposition  Polymerization Risk: None under normal conditions  Reactivity: Negligible at room temperature

Toxicological Information

Acute Toxicity: Not acutely toxic in solid form by ingestion, inhalation, or dermal contact  Chronic Effects: No evidence of carcinogenic, mutagenic, or reproductive effects under normal use  Irritation: Dust and particles can irritate eyes, nose, and skin  Thermal Decomposition: Vapors may cause headache, nausea, mucous membrane irritation  Key Facts: Molten polymer presents burn risk, dust exposure should be minimized

Ecological Information

Mobility: Sinks in water, pellets and dust can travel long distances if released  Persistence: Resistant to natural biodegradation  Bioaccumulation: Not expected to bioaccumulate significantly in aquatic life  Aquatic Toxicity: Not acutely toxic to fish or invertebrates in typical use forms  Other Environmental Issues: Risk of physical harm to wildlife if ingested or if entangled

Disposal Considerations

Disposal Methods: Recycle whenever possible, incinerate in approved facility if recycling not possible  Waste Classification: Non-hazardous solid waste by most regulations  Container Disposal: Clean thoroughly, recycle or dispose of empty containers according to local policies  Avoid: Open burning, uncontrolled landfill disposal, or release into waterways

Transport Information

UN Number: Not regulated as dangerous for transport  Transport Hazard Class: Non-hazardous goods  Packing Group: Not assigned  Labeling Requirements: No special transport labeling required  Other Transport Notes: Use clean, sealed transport; prevent cargo shifting, keep dry

Regulatory Information

OSHA Status: Not classified as hazardous under OSHA regulations for solid manufactured articles  TSCA Inventory: Listed  REACH Status: Polymer exempt from registration, specific monomers registered  SARA Title III: Does not contain reportable quantities  Other Requirements: Users should comply with local, state, and federal regulations concerning handling, recycling, and disposal